Reaction of diazoamino compounds with electrophiles using phase-transfer catalyst.
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Cycloruthenated compounds as efficient catalyst for asymmetric hydride transfer reaction*
Cycloruthenated complexes obtained by direct C–H activation of enantiopure aromatic primary and secondary amines are efficient catalysts in asymmetric hydride transfer reaction. Reduction of acetophenone has been achieved rapidly with enantiomeric excesses (ee’s) ranging from 38 to 89 %. The importance of Ru–C bond in the catalytic efficiency is highlighted.
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1989
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1989.1119